You can run OneDrive with a logon script and apply it to your users via a GPO.


Here is the FAQ regarding how to create a logon script :

https://support.tsplus.net/en/support/solutions/articles/44002126162-how-to-run-automatically-an-application-at-logon



Per example, we have added OneDrive and the Notepad to the logon script and both launch from the Application Portal when the user connects :

image



In the script all you need to do is add the path of the OneDrive exe in a text file that is named OneDrive.bat.

In our case, we added "C:\Program Files\Microsoft OneDrive\Onedrive.exe"


And added it like this: